Gigantic Thermal Shielding in 2D Oxide Nanosheets

Thermal shielding materials that can block near-infrared (NIR) light from the sunlight while maintaining visible transparency have become increasingly important from an energy-saving perspective. Here, we demonstrate a gigantic NIR shielding by an engineered plasmonic material based on a two-dimensional (2D) polytungstate (Cs_4–xW₁₁O_35–d). Starting from a charge-neutral polytungstate (Cs₄W₁₁O₃₅), we synthesize charge-imbalanced 2D nanosheets (Cs_4–xW₁₁O_35–d) that undergo an unusual structural change with the semiconductor-to-metal transition in a reduced atmosphere. Layer-by-layer engineering of the 2D nanosheets enables a plasmon-induced enhancement of the NIR reflectance (>53%) with a high visible transparency (>71%), realizing high-performance thermal shielding. Our approach offers a solution for future thermal management technology.